主题：高温高压矿物与材料研究
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材料科学与化学工程学院
2010．05．13
嘉宾简介：Jinfu Shu (束今赋)
CURRICULUM VITAE
Jinfu Shu (束今赋)
Address: Geophysical Laboratory
Carnegie Institution of Washington
251 Broad Branch Road, N.W
Washington, D.C.20015
Tel: 202-478-8963 (O)
Fax: 202-478-8901
Home Address: 10506 Hutting Place
Silver Spring, Maryland 20902
Tel: 301-942-9077
Date and Place of Birth: December 13, 1942; Shanghai, China
1961-1966 B.S.(Geology) Beijing College of Geology
1978-1981 M.S.(Mineralogy) Beijing College of Graduate School of Wuhan College of Geology
(China University of Geosciences )
1987-2010 Geophysical Laboratory, Carnegie Institution of Washington,
Research associates, postdoctoral fellow, senior fellow, research technician, research scientist
1987-Present Geophysical Laboratory, Carnegie Institution of Washington.
Experimental study of physical and Chemical behavior of Materials (single crystal and polycrystal)
Pertinent to the Earth’s and planetary interios at high pressure and temperature.
1986-1987 China University of Geosciences (Wuhan)
Director of x-ray laboratory, the Test Center.
Study of the meteorite shower in Xihezheng, Suizhou, Hubei, China,
and research on superconductor structure.
1982-1986 China University of Geosciences (Wuhan)
Research on the mineralogical and petrological characters of the igneous rock associations from Pan-Xi rift, Sichuan, China.
1978-1982 Beijing College of Graduate School of Wuhan College of Geology
Study of crystal structure and crystal chemistry of the minerals from alkaline rocks in Kola peninsula of USSR.
1967-1978 Geological Team of Hunan, China.
Geological field experience
Selected Publications:
1.X-ray Diffraction to 302 gigapascals: High-pressure crystal structure of cesium iodide
H. K. Mao, Y. Wu, R. J. Hemley, L. C. Chen, Jinfu Shu and L. W. Finger, High-pressure crystal
SCIENCE VOL 246 pp. 649-651, 1989
2.Elasticity and rheology of iron above 220 GPa and the nature of the earth’s inner core
Ho-kwang Mao, Jinfu Shu, Guoyin Shen, Russdll J. Hemley, Baosheng Li, & Anil K.Singh
NATURE VOL 396 pp. 741-743, 1998
3.The plastic deformation of iron at pressure of the Earth’s inner core
H.-R. Wenk, S. Matthies, R.J. Hemley, H.K. Mao & Jinfu Shu,
NATURE VOL 405 pp. 1044-1046, 2000
4.Phonon Density of States of Iron up to 153 Gigapascals
H.K. Mao, J. Xu, V.V. Struzhkin, J. Shu, R. J. Hemley, W. sturhahn, M.Y.Wu, E.E. Alp,
L.Vocadlo, D.Alfe, G.D. Price, M.J. Gillan, M.Schwoerer-Böhning, D. Häusermann, P. Eng,
G. Shen, H. Giefers, R.Lubbers, and G. Wortmann
SCIENCE VOL 292 pp. 914-916, 2001
5.Hydrogen clusters in clathrate hdryate
Wendy L. Mao, Ho-kwang Mao, Alexander F. Goncharov, Viktor V. Struzhkin, Quanzhong Guo,
Jingzhu Hu, Jinfu Shu, Russell J. Hemley, Maddury Somayazulu,Yusheng Zhao,
SCIENCE VOL 297 pp. 649-651, 2002
6. Bonding changes in compressed superhard graphit
Wendy L. Mao, Ho-kwang Mao, Peter J. Eng, Thomas P. Trainor, Matthew Newville, Chi-Chang Kao,
Dion L. Heinz, Jinfu Shu, Yue Meng, Russell J. Hemley,
SCIENCE VOL 302 pp. 425-427, 2003
7. Iron-rich post-perovskite and origin of ultralow-velocity zones
Wendy L. Mao, Ho-kwang Mao, Wolfang Sturhahn, Jiyong Zhao, Vitali B. Prakapenka, Jinfu Shu,
Yingwei Fei, and Russell J. Hemley,
SCIENCE VOL 312 pp. 564-565, 2006
8. X-ray-induced dissociation of H2O and formation of an O2- H2 alloy at high pressure
Wendy L. Mao, Ho-kwang Mao, Yue Meng, Peter Eng, Michael Y, Hu, Paul Chow, Yong Q.Cai,
Jinfu Shu, Russdll J. Hemley
SCIENCE VOL 314 pp. 636-638, 2006
Selected Publications in Other High Profile Journals:
9. High-Pressure Phase Transition and Equation of State of CsI
Physical Review Letters Volume 64, Number 15 pp. 1749-1752, 1990
H.K. Mao, Y. Wu, R.J. Hemley, L.C. Chen, J. F. Shu, L.W. Finger, and D.E. Cox
10. Low-Frequency Vibration Dynamics and Structure of Hydrogen at Megabar
Physical Review Letters Volume 65, Number 21 pp. 2670-2673, 1990
R.J. Hemley, H.K. Mao, and J.F. Shu
11. New High-Pressure Excitations in Parahydrogen
Physical Review Letters Volume 80, Number 10 pp. 101-104, 1998
Alexander F. Goncharov, R.J. Hemley, Ho-kwang. Mao, and Jinfu Shu
12. Estimation of Single-Crystal Elastic Moduli from Polycrystalline X-ray Diffraction
at high pressure: application to FeO and iron
Physical Review Letters Volume 80, Number10, pp. 2157-2160, 1998
Singh, A.K., H.K. Mao, J. Shu, and R.J. Hemley
13. Pressure-Induced High-Spin to Low-spin Transition in FeS Evidenced by X-ray Emission
Spectroscopy
Physical Review Letters Volume 82 pp. 3284-3287, 1999
Rueff, J.-P., C.-C. Kao, V.V. Struzhkin, J.Badro, J. Shu, R.J. Hemley, and H.K. Mao
14. Magnetism in FeO at Megabar Pressure from X-Ray Emission Spectroscopy
Physical Review Letters Volume 83, Number 20, pp. 4101-4104, 1999
James Badro, Viktor V. Struzhkin, Jinfu Shu, Russell J. Hemley, and Ho-kwang Mao
15. Nuclear Inelastic X-Ray Scattering of FeO to 48 Gpa
Physical Review Letters Volume 87, Number 25, 2001
Viktor V. Struzhkin, Ho-kwang Mao, Jingzhu Hu, Markus Schwoerer- Böhning, Jinfu Shu,
Russell J. Hemley, Wolfang Sturhahn, Michael Y. Hu, Ercan E. Alp, Peter Eng and Guoying Shen
16. Ordering of Hydrogen Bonds in High-Pressure Low-Temperature H2O
Physical Review Letters, 025502, 2005
Y.Q. Cai, H.-K.Mao, J.P.C. Chow, J.S. Tse, Y. Ma, S. Patchkovskii, Jinfu Shu, V. Struzhkin,
R.J. Hemley, H.Ishii, C.C. chen, I.Jarrige, C.T. Chen, S.R. Shieh, E.P. Huang, and C.C.Kao
17. Phase Transition of Vanadium at 69 GPa
Physical Review Letters 98 085502 2007
Yang Ding, Rajeev Ahuja, Jinfu Shu, Paul Chow, Wei Luo, and Ho-kwang Mao
18. Structure of alkali borate glasses at high pressure: B and Li K-edge inelastic x-ray scattering study
Physical Review Letters 98 100502 2007
Lee S. K., P. J. Eng, H. K.Mao, Y. Meng, and Jinfu Shu
19. Origin of Pressure-Induced Polymorphism in Ce75Al25 Metallic Glass
Physical Review Letters 104, Number 20, 10572, 2010
Qiao-shi Zeng, Yang Ding, Wendy L. Mao, Wenge Yang, Stas.V. Sinogeikin, Jinfu Shu,
Ho-kwang Mao and J.Z. Jiang
20. Fossilized high pressure from the Earth’s deep interior: The coesite-in-diamond barometer
Proc. Natl. Acad. Sci. PNAS, Vol. 97, No. 22 pp. 11875-11879, 2000
Nikolai V. Sobolev, Boris A. Fursenko, Sergei V. Goryainov, Jinfu Shu, Russel J. Hemley,
Ho-kwang Mao, and Francis R. Boyd
21. Transformations in Methane hydrates
Proc. Natl. Acad. Sci. PNAS Vol. 97 no.25 pp. 13484-13487, 2000
I-ming Chou, Anurg Sharma, Robert C. Burruss, Jinfu Shu, Ho-kwang Mao, Russel J. Hemley,
Alexander F. Goncharov, Laura A. Stern, and Stephen H. Kirby
22. Natural occurrence and synthesis of two new postspinel polymorphs of chromite
Proc. Natl. Acad. Sci. PNAS, 100, 14651-14654, 2003.
Chen, M., Jinfu Shu, H. K. Mao, X. Xie, and R. J. Hemley
23. Space weathering on airless planetary bodies: Clues from the lunar mineral hapkeite
Proc. Natl. Acad. Sci. PNAS, Vol.101, No.18, pp. 6847-6851, 2004
Mahesh Anand, Lawrence A. Taylor, Mikhail A. Nazarov, Jinfu Shu, H. K. Mao, and R. J. Hemley
24. Electronic spin state of iron in the Earth's lower mantle perovskite
Proc. Natl. Acad. Sci. PNAS, Vol.101, No.39, pp.14027-14030, 2004
Jie Li, Viktor V. Struzhkin, Ho-Kwang Mao, Jinfu Shu, Russell J. Hemley, Yingwei Fei,
Bjorn Mysen, and Prezmek Dera, Vitali Prakapenka, and Guoyin Shen
25. Ferromagnesian postperovskite silicates in the “D" layer of the Earth
Proc. Natl. Acad. Sci. PNAS, Vol.101, No.45, pp.15867-15869, 2004
Wendy L. Mao, Guoyin Shen, Vitali B. Prakapenka, Yue Meng, Andrew J. Campbell,
Dion L. Heinz, Jinfu Shu, Russell J. Hemley, and Ho-kwang Mao
26. Iron-Rich silicates in the Earth’s D’ layer
Proc. Natl. Acad. Sci. PNAS, Vol.102, pp. 9751-9753, 2005
Wendy L. Mao,Y. Meng,G. Shen, V.B. Prakapenka, A.J. Campbell, D.L. Heinz, J. Shu
R.Caracas, R.E.Cohen, Y. Fei, R. J. Hemley, and H.K. Mao
27. X-ray Raman scattering study of MgSiO3 glass at high pressure: implication for triclustered
MgSiO3 melt in Earth’s mantle
Proc. Natl. Acad. Sci. PNAS, Vol.105, 7925-7929 2008
S.K. Lee, J.-F. Lin, Y.Q. Cai, N. Hiraoka, P.J. Eng, T. Okuchi, H.K. Mao, Y. Meng,
M.Y.Hu, P. Chow, J. Shu,B. Li, H. Fukui, B. M. Lee, H.K. Kim, and, C.-S. Yoo.
28. Inelastic x-ray scattering of dense solid oxygen: evidence for intermolecular bonding
Proc. Natl. Acad. Sci. PNAS, Vol.105, 11640-11644 2008
Y. Meng, P.J. Eng, J.S. Tse, D.M. Shaw, M.Y. Hu, J. Shu, S.A. Gramsch, C.-C. Kao,
R.J. Hemley, and H.K. Mao,
29. Substitution ally of Ce and Al.
Proc. Natl. Acad. Sci. PNAS, Vol.106, 2515-2518 2009
Q.-S.Zeng, Y. Ding, W.L. Mao, W.L. Luo, A. Blomqvist, R. Ahuja, W. Yang, J. Shu,
S.V. Sinogeikin, Y. Meng, D.L. Brewe, J.-Z. Jiang, and H.K.Mao
30. Nanoprobe measurements of materials at megabar pressures
Proc. Natl. Acad. Sci. PNAS, Vol.1 2010
Lin Wang, Yang Ding, Wenge Yang, Wenjun Liu, Zhonghou Cai, Jennifer Kung,
Jinfu Shu, Russell J. Hemley, Wendy L. Mao, and Ho-kwang Mao
31. The formation of sp3 bonding in compressed BN
Nature Materials Vol. 34 pp.111-114, 2004
Yue Meng, Ho-kwang Mao, Peter J. Eng, Thomas P. Trainor, Matthew Newville, Michael Y. Hu,
ChiChang Kao, Jinfu Shu, Daniel Häusermann, and Russell J. Hemley
32. Probing of Bonding Changes in B2O3 glasses at high pressure with inelastic X-ray scattering
Nature Materials Vol. 4 pp.851-854, 2005
Sung keun Lee, Peter J. Eng, Ho-kwang Mao, Yue Meng, Matthew Newville, Michael Y. Hu,
and Jinfu Shu
And other main reference:
(1). The crystal structure of barytolamprophyllite (Chinese)
China University of Geosciences Xuebao (1983)
Jinfu Shu, Zhizhong Peng, Jianhong Zhang
(2). The crystal structure of barytolamprophyllite (English)
Kexue Tongbao, 29, pp.237-241(1984)
Zhizhong Peng, Jianhong Zhang and Jinfu Shu
(3). The Crystal Structure of the Seramic Superconductor of the Y-Ba-Cu-O Compounds
Z. Phys. B-Condensed Matter 69, pp. 29-31, 1987
J.F. Shu and J.C. Shen, K.L. Yao, J.W. Liang, Z.Y. Hey, E.G. Wang, B.R. Li, M.Y. Ye,
H.L.Wang, and Z.Q. Zheng
(4). Discovery of LaCeNbSiO3 and Mineralogy Study
(1989) (award in 1990 Hubai)
J. X. Gu, S.X. Tang, G. Y. Gao, and J.F. Shu
(5). High pressure DAC studies on undoped La2CuO4
Pysica C 176 pp. 503-506, North-Holland, 1991
Jinfu Shu, Jagannadham Akella, J.Z. Liu, Ho Kwang Mao and Larry W. Finger
(6). A New Superhard Form of Carbon
AGU EOS Vol. 36 No.3 pp. 479 (1991)
J.F.Shu H.K. Mao, J.Z.Hu, Y.Wu, R.J. Hemley
(7). Single crystal x-ray diffraction of stishovite to 65 Gpa
AGU meeting EOS, 75 pp. 662,1994
H. Mao, J. Shu, J. Hu, and R.J. Hemley
(8). Wustite FeO and Magnesiowustite (Mg,Fe)O Synchrotron X-ray diffraction Study
The 30th International Geologic Congress Beijing China 1995
J.F. Shu, H.K. Mao, and R.J. Hemley
(9). High-pressure phase transition in magnesiowustite (Fe1-x O)
EOS Trans AM Geophys. Union 79 S203, 1998
J.F. Shu, H.K. Mao, R.J. Hemley
(10). Single-Crystal X-ray Diffraction of Wustite to 30 Gpa Hydrostatic Pressure
Neues Jahrb. Mineral. Abh. 172 pp. 309-323, 1998
Jinfu Shu, Ho-Kwang Mao, Jingzhu Hu, Yingwei Fei and Russell J. Hemley
(11). High-Pressure Phase Transformation in MnF2
AIRAPT-17 1999
J.F. Shu, H.K. Mao, R.J. Hemley
(12). Single-Crystal X-ray Diffraction of New Methane Hydrates
AIRAPT-18 2001 in Beijing China pp. 23, 2001
Jinfu Shu, Hokwang Mao, Jingzhu Hu, RusselHemley, and I.Ming Chou
(13). Micromineral study by Synchrotron X-ray Diffraction
The 4th World Chinese Conference on Geological Science, Nanjing China 2002
Abstracts pp.227
Jinfu Shu, Ho-kwang Mao, Russel J.Hemley
(14). Single-Crystal X-ray Diffraction of New Methane Hydrates
Brookhevan Nationnal Laboratory 2002
Jinfu Shu, Ho-kwang Mao, Jingzhu Hu, Russel J.Hemley, I-Ming Chou
(15). New mineral discovery and micro-minerals study using synchrotron x-ray diffraction
2004 in Hainan, China
Jinfu Shu, Ho-kwang Mao, Russell J. Hemley
(16). Pressure-Induced Distortive phase Transition in Chromite-spinel at 29GPa
Mater.Res.Soc.Symp.Proc.Vol.987 179-184 2007
Jinfu Shu, Wendy L. Mao, Russell J. Hemley, Ho-kwang Mao
(17). Structure stability of methane hydrate at high pressure
The 5th Asian conference on high pressure research Soul Korea 2008
Jinfu Shu, Xiao-Jia Chen, I-ming Chou, Wenge Yang, Jingzhu He, Russell J. Hemley,
and Ho-kwang Mao
(18). Mineralogy under extreme conditions.
For International Workshop on Multiple-scale Geodynamicsof Continetal Interiors. 2010
Jinfu Shu, Ho-kwang Mao
Since 1987, I came from Beijing, China to United State, Carnegie Institution of Washington, Geophysical laboratory, until now already 23 years.
In the Carnegie Institution of Washington, Geophysical laboratory, I have learned lot of high pressure and high temperature science and technology, I have got rich experience in practice, I also help lots people do something; and I have did lots of work and got many very good results
A. Ultrahigh pressure (above 300 Gpa) and very high temperature (above 5000K) Synchrotron x-ray diffraction and low mantle, low mantle-core, and core conditions
1. Ultrahigh-pressure Experimentation Above 300 GPa [Fe, FeNi, W, Pt, C (Grphite)], etc.
2. X-ray Diffraction to 302 Gigapascals: High-Pressure Crystal Structure of Cesium Iodide
3. Pressure Calibration to 304 Gpa on the Basis of X-ray Diffraction Measurements of Pt, Fe and CsI
4. Static Compression of Iron to 300 GPa and Fe0.8Ni0.2 Alloy to 260 Gpa: Implication for Composition
of the Core
5. Electronic spin state of iron in the Earth's lower mantle perovskite
6. In situ X-ray diffraction studies of iron to Earth-core conditions
7. The effect of pressure on the structure and volume of ferromagnesian post-perovskite
8. Ferromagnesian postperovskite silicates in the “D" layer of the Earth
9. High-pressure sound velocities and elasticity of aluminous MgSiO3 perovskite to 45 GPa:
Implications for lateral heterogeneity in Earth” lower mantle
10. The effect of pressure on the structure and volume of ferromagnesian post-perovskite
11. Iron-Rich Post_Perovskite and Origin of Ultralow-Velocity Zones
12. Deformation of Lower-Mantale Ferropericlase across the Electronic Spin Transition
B. High pressure and high temperature Synchrotron x-ray diffraction and phase transition, Equation of state study
1. Compressibility and Thermal Expansion of (Mg,Fe)SiO3 Perovskite at High Hydrostatic Pressures
(Mg,Fe)SiO3 pressure-induced structure phase transition
2. High-pressure phase transition and equation of state of Lead to238 GPa
3. High-pressure phase transition and equation of state of CsI
4. Determination of lattice parameters of b-phase and perovskite under Simultaneous high-pressure
and high temperature conditions
5. Effect of Pressure, Temperature, and Composition on lattice Parameters and Density of
(Fe,Mg)SiO3-Perovskites to 30 GPa
6. A New Superhard Form of Carbon
7. P-V-T Equation of State of Magnesiowustite (Mg0.6Fe0.4) O
8. High-pressure phase transition in wustite and magnesiowustite (Fe1-x O)
9. Pressure-Induced High-Spin to Low-spin Transition in FeS Evidenced by X-ray
Emission Spectroscopy
10. Pressure-induced structure phase transition in CuIr2Se4
11. The Rhombohedral Phase Transitions of CoO under Hydrostatic High-Pressures
12. Phase transition and compression behavior of gibbsite under high-pressure
13. The effect of pressure on the structure and volume of ferromagnesian post-perovskite
14. Phase Transition of Vanadium at 69 Gpa
C: Single crystal x-ray diffraction by common four-circle x-ray diffractometer and Synchrotorn radiation source:
1. High-pressure crystal chemistry of Stishovite
2. High pressure DAC studies on undoped La2CuO4
3. H2, D2 synchrotron single crystal x-ray diffraction analysis
4. Singe-Crystal X-ray Diffraction of Brucite to 14 Gpa
5. Single crystal x-ray diffraction of wustite to 30 Gpa hydrostatic pressure
6. Single crystal x-ray diffraction of Stishovite to 65 Gpa and new CaCl2 type post-stishovite
phase transition
7. High-Pressure Phase Transformation in MnF2
8. Monohydrate L-asparagine single x-ray diffraction
9. H type methane hydrate single x-ray diffraction study
10. II type methane hydrate single x-ray diffraction analysis
11. Chromite FeCr2O4 single crystal x-ray diffraction study and new phase transiation
D: Diamond anvil cell radial x-ray diffraction:
1. Hydrostatic pressure, deviatoric stress, and phase transition
2. X-ray Imaging of Stress and Strain of diamond, Iron and Tungsten at Megabar Pressures
3. Estimation of Single-Crystal Elastic Moduli from Polycrystalline X-ray Diffraction
at high pressure: application to FeO and iron
4. Analysis of lattice strains measured under nonhydrostatic pressure
5. Interpretation of the lattice-strains measured under non-hydrostatic pressure
6. Elasticity and rheology of iron above 220 Gpa and the nature of the earth’s inner core
7. Lattice strain in gold and rhenium under nonhydrostatic compression to 37 GPa
8. Elasticity, shear strength, and equation of state of molybdenum and gold from x-ray diffraction
under non hydrostatic compression to 24 Gpa
9. The plastic deformation of iron at pressure of the Earth’s inner core
10. Deformation of polycrystalline MgO at Pressures of the lower mantle
11. Strength, anisotropy, and preferred orientation of solid argon at high pressures
E: Synchrotron nuclear inelastic x-ray scattering
1. Phonon desity of states of iron to 153 GPa
2. Nuclear Inelastic X-Ray Scattering of FeO to 48 Gpa
3. Electronic spin state of iron in the Earth's lower mantle perovskite
4. Nuclear resonant x-ray scattering of iron hydride at high pressure
5. Probing of Bonding Changes in B2O3 glasses at high pressure with inelastic X-ray scattering
6. Structure of alkali borate glasses at high pressure: B and Li K-edge inelastic x-ray scattering study
7. Inelastic x-ray scattering of dense solid oxygen: evidence for intermolecular bonding.
8. Experimental determination of the elasticity of iron at high pressure.
9. Probing of modeling of pressure-induced coordination transformation in borate glasses: inelastic
x- ray scattering study at high pressure.
F: New mineral discovery and micro-mineral study using synchrotron x-ray diffraction
(I). New mineral:
1. Tuite: A High pressure phase of g-Ca3 (PO4)2 (in the shock melt veins of the Suizhou meteorite)
2. Hapkeite: New lunar Mineral (Fe2Si): product of Impact-Induced Vapor-Phase Deposition
3.Two new postspinel polymorphs of chromite (xilite):
a. CaFe2O4-type high pressure chromite
b. CaTi2O4-type high pressure chromite
4. New mineral Fe3Si7 from Tibet, China
5. New mineral Luosaite
(II). Micro-mineral synchrotron x-ray diffraction study
1. Magnetite lamellae in olivine and clinohumite from Dabie UHF ultramafic rocks, Central China
2. Fossilized high pressure from the Earth’s deep interior: The coesite-in-diamond barometer
3. The cell parameters of zoned topaz is a function with F and OH
4. Diamond inclusion from Tibet, China and the Chinese Continental Scientific Drilling Project Main Hole
(CCSD-MH)
